Hustle Kings

In order to unlock this trophy you'll be required to execute a Swerve or Jump shot to pocket a ball. This is only unlocked Offline so far as I know. Here is a video for reference on the Jump Shot:

- Jump Shot -
(Credit to brutaldemise for the video)

The easiest way to unlock this trophy is to wait until a ball is hovering right over the pocket. Now jump the cue ball over whatever is in between and pot the ball, this makes it hard to miss.