PAIN

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First, you'll need to have purchased the Movie Studio level from the PSN store or the Pain store. Next, you'll need to unlock After Party by destroying every movie set in the level. Once you've unlocked After Party, you need to get a score of 3 million to unlock Buzz. Once you have Buzz, you'll need to unlock Spank the Monkey Painful, which you may have already done if you were working on King of Pain. Finally, you need to hit 60 monkeys on the Painful level to get the trophy. This will take a while to learn where all the monkeys pop up, and you'll need to get as many of them in one run as possible at the start to give yourself enough time to get the harder ones later.