Spider-Man: Edge of Time

In order to get this achievement you need to get gold medals on all the challenges in one act. Out of the three acts the first one is easiest, and it should be noted that you need to do all the chapters within the act, not just a single chapter of challenges. Just follow the web to the center to see which act the challenge belongs to, but they are grouped in chronological order.

For a more in depth detail look into the Consumate Completist achievement.