Batman: Arkham Origins

Story Related and cannot be missed.

You will find yourself in a Hotel. When you reach the top, you will get into a fight with Bane, who is extremely strong due to Titan. You'll need to use ultra stuns (,,) followed by beatdowns (mash ) to inflict damage on him. When you have an orange combo meter, use the Combo Takedown (+) to partially destroy his titan canister.
The fight will eventually move to a rooftop, where Bane will go crazy and be incredibly hard to hit. Use the other enemies to increase your combo, then do the same Cmbo Takedown as before. There are also times where he is still, so you can use the ultra stun and beatdown combo. Repeat until the fight ends. After the resulting cutscene the trophy will unlock