Blazing Angels

To do this will need to get "Ace" ranking on all mission, and there are 18 missions in total. You can check which missions you've aced by going in your stats and selecting "Medals". For each level you have a medal in you will have gotten an "Ace" ranking as well.

Getting an Ace rank in each mission requires you to meet certain requirements for each mission, which can be divided into four categories. Time taken to finish the mission, pilots killed, ground units destroyed, and naval units destroyed. Time is always a factor, though most missions will not always have all three enemy types. For each enemy type available, there will be a certain amount you need to kill in order to achieve the Ace ranking requirement in that category. If you do extremely well in one category, you will have some leeway if you don't do as well in the other categories.  

Using cheats, getting a majority of the missions finished with an Ace rank isn't too hard, but you will still struggle on a mission or two. The only thing you can do is PRACTICE! If you take the time to learn how each level plays out, and where all of the enemies will be coming from, it'll make things a lot easier on you. Also remember, that if you find yourself struggling in one area, do your best to excel in another. For example, if you always beat a mission a minute above par time, take an extra minute or two to take down as many enemies as you can, or vice versa. This can turn a bad run into an Ace rank, and should always be kept in mind. 

*Note: This achievement will be gotten at the same time as "Hero"