ELEX

There are 3 separate achievementsfor maxing out the skills of each faction, outlaws, berserkers and Clerics.

There is a method to obtain all 3 in one playthrough provided you haven't already joined a faction.

Get to a point in the game where you have offers to join from all three factions. Aim for getting Strength, Dexterity, to 85 and the rest to 70. make A separate Save before you begin Craft enough Strong Elix potions so you can have 20 skill points spare and craft about 100 Elex potions drink them but dont assign them yet and have about 25k currency spare. now make a second save.

Remember that each Elex potion you drink gives 2 attribute points and each Strong Elex Potion you drink gives you a Skill point. You can Buy the recipe 'craft Elix potions' from Alrik in Goliet and buy the recipe 'craft strong Elix potions' from Caldrim also in Goliet.

Now visit the Clerics and agree to join, now go straight into the room opposite and talk to Baldur, buy each of the skills, if you need to more points in an attribute then use them. I believe 85 iNTELLIGENCE is highest for Clerics.
Once you have the achievement, reload your second save and this time join the berserkers, then finally reload again and join the Outlaws.

You can acquire all the skills immedietly upon joining it just requires high enough skill lvels and enough spare Skill points.

In response to a comment 'is there enough experience to earn all skills in 1 playthru'?

Forgetting levelling up, it will take forever to get enough attribute and skill points. I completed the game at level 25, levelling is only important in the early to mid stage of the game.After this the key is Elex potions. The quickest way to boost your attributes points is creating and drinking ELEX potions at a workbench, each drink gives 2 attribute points. Also purchase the skills Animal trophy 1,2 & 3. They give you a tonne of trophies for each kill, all of these trophies can be sold. I recommend to grab the redeemer weapon. Go on a Kill spree and sell all the animal trophies and purchase natural elex and create elex potions at a work bench. Visit Anna at the ORIGINS CAMP AND purchase the TRADER and workbench. The trader has an infinite amount of Natural Elex. Sell all the animal trophies, purchase Natural Elex then create the ELex potions.
if you create 100 Elex potions that will give you 200 attribute points this is by far the quickest and easiest method of getting attribute poiints, levelling up will take far too long.

Preparation:
i was following a guide that recommended to increase all attributes to 40 ASAP. i just finished doing all the side quests and main quests and companion quests available before choosing a faction .
so i had everything done and couldn't progress to chapter 2 until choosing a faction. i was lvl 27 at this point with my attributes at 40.

now i used the infinite money glitch at the armor smith in goliet next to the blacksmith teleporter. i was ending up with around 35000 elexit, buying natural elex and liquor then using the exploit again.
infinite money glitch:

you need at least 360 liquor and 840 natural elex for all of these skill achievements.

doc sells natural elex 16 at a time, infinite back to back transactions. i bought the liquor (100 at a time, infinite back to back transactions) from the trader at my origin camp. (buy trader from annie at origin for 1000 elexit)
i bought the chemistry ability from a crafting trainer, and the strong elex potion and elex potion recipes (ignore small elex drink).
then i made at docs workstation at the fort, 20 strong Elex Drink and 160 Elex drinks.

Warning! if going for the Human achievement DO NOT consume any elex drinks. elex drinks RAISE COLD level.

with all the elex drinks in hand and a good amount of elex. make 2 or 3 manual save slots to go back to if you want to.
AFTER YOU SAVE drink all the elex drinks you made and you should have hundreds of attribute points and alot of learning points. your cold will probably now be at intuitive as well.
DO NOT TOUCH THE MANUAL SAVES FROM BEFORE DRINKING THE ELEX. make another save after drinking all the elex so you won't have to drink them each time.

your all set to go for the specific achievement see below for this achievement specifics.
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Outlaw:
go to William near the front of the fort and join the outlaws, you can now learn all outlaw abilities right away from william. you need attributes like this: Strength 60, Constitution 85, Dexterity 70, Intelligence 50, Cunning 50. and enough elexit to buy the abilities from william (see money glitch above)

i had 84 attribute points and 29 ability learning points left after getting the achievement.

Post-achievo: reload the save from after drinking all the elex if still going for all the other achievements, or continue the game as normal.