Mato Anomalies

Once you hit Level 31, you should have just enough skill points to unlock all of the different skills available for each character. I was actually this level right when I got the final party member (Ringless), but I had spent some extra points on Butterfly's poison skills and did not have one of her talents. The only nodes you need to purchase to get this achievement are each of the ones that specifically say "New Skill: X" and there is one each in the Yang and Yin skill trees for each character. For instance, Gram's are "New Skill: Berserk" in Yang and "New Skill: Blood Boil" in Yin. You have to spend 11-14 points in each skill tree before the nodes with the new skills are available, and you also need the Ultimate ability for every character as well.

You will likely be near Level 45-50 when the game is complete, and you can reset all your talent points for a small fee of gold (which increases every time you do it), so there isn't any way to lock yourself out of this by investing points in a single tree until you want the achievement.